The William Murdoch Archive

1795 - Discovers Isinglass substitute for refining beer


(Picture by BBC Education)


REFFERENCES :

Adapted from the book "The Third Man" by John Griffiths (1992)

William's estimate of his standing as a chemist emerges in a reply he gave to Counsel in a trial in 1809-10 relating to another of his chemical discoveries. 

In 1795 he had developed a cheap substitute for Russian isinglass, the precipitant made from sturgeon for "fineing" or clarifying beer by removing suspended particles of tannin or other foreign matter. 

The increase in price of the Russian product in a very short time from three shillings a pound to twenty-five shillings a pound made the development of a British alternative, even if not quite as effective, economically attractive. 

There is a delightful story told by Smiles of William, on one of his trips to London, experimenting in his lodgings with the cod skins soaked in stale beer, which he was seeking to substitute for the sturgeon product, and hanging them on the curtains of his room to dry. 

His landlady, horrified at the use to which her hangings were being put, immedietly threw William out, codfish skins and all. 

He cannot eventually have felt too aggrieved, for in due course the Committee of the London Brewers paid him two thousand pounds for the right to use the substitute. 

In 1809 Customs & Excise, encouraged by the Solicitor General, began one of those absurd prosecutions for which the English legal system is celebrated, bringing a case against two sample brewers for adulterating their beer by adding the Murdoch fineing substitute which the Excise officers classified as both fish and stale beer. 

The Solicitor General, cross-examining William, tried the belittling technique with which Wiliam would have long been familiar from the Watt patent cases, but which had little effect in this instance. 

SG : "What profession are you of?" 
WM : " A steam engineer." 
SG : "You are not a physician?" 
WM : "I am not." 
SG : Nor a Chymist?" 
WM : "No - in a small degree but not a professional Chymist"
Nevertheless, William's "small degree" was quite sufficient to provide the factual chemical evidence needed to flatten the prosecution case by pointing out that the addititive, like it's predecessor, precipitated the impurities in the beer before sinking them to the bottom of the vessel, and could not therefore be said to be added to the beer. To drive this point home he replied to one question : "About fourteen years since I practiced it and lately in my own house."

The value and harmlessness of the substitute was vouched for in evidence by Humphry Davy : 

Q : "Mr. Davey we all know that you are eminently skilled in chemistry - are you aquainted with this recipe of Mr Murdock?" 
HD : "Yes." 
Q : "From your knowledge upon this subject is it proper to be used for the purpose of fineing beer?" 
HD : "I believe it is if properly prepared - it is the same substance as Isinglass."
The prosecution's next trick was to produce an obnoxious smelling bottle of the offending addititive, collected many months before, in order to convince the Court of its deleterious effects. With William's help, the Brewers' counsel, Mr Raine, scothched that ploy in re-examination : 
Mr R : "Supposing old Isinglass dissolved had been seized in May and kept until September would it be as sweet in September as in May?" 
WM : "I believe not." 
At that point the judge intervened : 
COURT : "There is nothing likely to be so offensive as Isinglass dissolved and kept in a bottle, is it not so?" 
WM "It is."
The judge, with a nice touch of patriotism, called William's version "Isinglass made of British fish", and in his summing up commiserated with the Brewers "in having incurred blame where to me they had merit." 

He concluded "I happened to know of this British Isinglass many a day before I came into Court - I have heard of it many months ago - I have heard it spoken of by men of science as a very advantageous discovery." 

Not surprisingly, Customs & Excise lost their prosecution.

Written by John Griffiths
Adapted by Franco Varani
November 2000
Chronology